HANDBOOK OF HYDROCOLLOIDS PDF
HANDBOOK OF HYDROCOLLOIDS. Second edition. Edited by G.O. Phillips and P.A. Williams. Woodhead Publishing in Food Science,. Technology and. Handbook of hydrocolloids Related titles from Woodhead's food science, technology and nutrition list: New ingredients. Request PDF on ResearchGate | Handbook of Hydrocolloids | Introduction. Agar. Starch. Gelatin. Carrageenan. Xanthum Gum. Gellan Gum. Gallactomannans.
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Request PDF on ResearchGate | Handbook of Hydrocolloids: Second Edition | Hydrocolloids are among the most widely used ingredients in the food industry. Purchase Handbook of Hydrocolloids - 2nd Edition. DRM-free (EPub, PDF, Mobi) Hydrocolloids are among the most widely used ingredients in the food. The consent of CRC Press LLC does not extend to copying for general refer to frequently as my Handbook of Medi Building Construction Handbook.
Coverage of microbial polysaccharides has also been increased and the developing role of the exudate gums recognised, with a new chapter on Gum Ghatti. Protein-polysaccharide complexes are finding increased application in food products and a new chapter on this topic as been added. Two additional chapters reviewing the role of hydrocolloids in emulsification and their role as dietary fibre and subsequent health benefits are also included.
The second edition of Handbook of hydrocolloids is an essential reference for post-graduate students, research scientists and food manufacturers. Introduction to food hydrocolloids Hydrocolloids and emulsion stability The health aspects of hydrocolloids Agar Starch Gelatin Carrageenan, furcelleran and other seaweed-derived products Xanthan gum; Gellan gum Galactomannans Gum Arabic Pectins Milk proteins Egg proteins Vegetable protein isolates Protein-polysaccharide complexes and coacervates Gum Ghatti Other exudates: Tragancanth, karaya, mesquite gum and larchwood arabinogalactan Xyloglucan Curdlan Other microbial polysaccharides: Pullulan, scleroglucan, elsinan, levan, alternan, dextran etc.
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Skip to content. Search for books, journals or webpages All Webpages Books Journals. View on ScienceDirect. Hardcover ISBN: In general, the rheological test methods for the assessment of gel characteristics can be grouped into three types namely, fundamental, imitative and empirical. Each has certain advantages and a few limitations. Fundamental methods Fundamental small deformation tests involve dynamic oscillatory rheometry, creep test and stress relaxation test.
In dynamic oscillatory rheometry, the sample is subjected to an oscillatory stress-strain of frequency. These parameters are very important for the rheological characterization of gels. Its value is given by the formula. Another important test is the creep test. Gel, being a viscoelastic material, responds to the creep test with a nonlinear strain. The important property measured during creep test is the ratio of strain to stress as a function of time, and is referred to as the creep compliance.
It describes how compliant a material is; the greater the compliance, the easier it is to deform the material. Stress relaxation is another important study in the rheology of food. If a gel sample is deformed by a fixed strain and held there over a long time interval, the stress required to maintain this constant strain will gradually decrease due to relaxation of the sample. The sample under testing will only partially recover its original geometry.
Handbook of Hydrocolloids
The relaxation modulus is an important rheological property measured during stress relaxation. It is the ratio of the measured stress to the applied initial strain. These parameters are usually determined by constant speed experiments such as uniaxial compression and uniaxial tension performed on texture measuring systems.
Compression test and tensile tests are generally performed in this study. Empirical methods Compression or penetration tests constitute the basis of many small-deformation empirical tests used to measure gel strength.
The most common parameter used to measure gel quality is gel strength. The choice of instrument for gel measurement will depend on whether a single-point or multi-parameter analysis.
It is governed by factors like high-speed data acquisition, precision and accuracy of results. Large-deformation empirical tests are used to measure another parameter of gels known as rupture strength i. Imitative methods The single point measurements, often based on rupture tests, are not representative of the overall mechanical behaviour of gels. A much more comprehensive understanding of gel texture is obtained by analysis of the force-deformation curve generated by compressing a gel sample using a texture measuring system.
This instrumental technique is known as texture profile analysis. It is a technique based on compression of free-standing gels twice in succession and is capable of providing both fundamental and empirical data on the mechanical properties of gels. It has the advantage of providing data at both low and high strains allowing gels to be characterised by multiple parameters. The flowable materials like thin and thick dispersions are conventionally examined employing a viscometer or rheometer.
Generally, the shear rate-stress data are collected over a wide range along with the measurement of apparent viscosity, yield stress, zero-shear and high-shear viscosities. A number of available rheological models are used to calculate model parameters like consistency index and flow behaviour index and these parameters help in the characterisation of the samples.
Conclusions As an important food additive, hydrocolloids are finding increasing applications in several food products as thickening and gelling agents. The thickening effects are mainly provided by carboxymethyl cellulose, methyl cellulose and hydroxypropylmethyl cellulose, guar gum, locust bean gum, tara gum, konjac maanan, gum tragacanth, gum ghatti and gum Arabic.
The frequently used gelling agents include modified starch, agar, carrageenans, pectins, gellan gum, alginates and methyl and hydroxypropylmethyl celluloses. The role of each hydrocolloid in food formulations and product development has been discussed along with examples and methods of characterisation to indicate the increasing use of hydrocolloids as an important food additive.
Effect of carrageenan on yield and properties of tofu.
Food Chem. Melt-in-the-mouth gels from mixtures of xanthan and konjac glucomannan under acidic conditions—a rheological and calorimetric study of the mechanism of synergistic gelation. Carbohydr Polym. Generation of engineered structures in gels. Physical chemistry of foods. New York: Marcel Dekker; Hydrocolloid gums. Part I: Natural products. Cereal Foods World. Part II: Synthetic products. Acetylation and characterisation of corn starch. J Food Sci Technol.
Int Dairy J. Effect of addition of sucrose and aspartame on the compression resistance of hydrocolloid gels. Int J Food Sci Technol. Factors affecting the emulsifying and rheological properties of gum acacia in beverage emulsions. It is mainly the hydrocolloid providing a Alexander a.
Hydrocolloids as thickening and gelling agents in food: a critical review
Thickening of sweet and Ketchup is one of the most common food items where sour sauces with various polysaccharide combinations like the hydrocolloid thickeners are used to influence its potato starch-xanthan gum and oat starch-xanthan gum has viscosity.
Sahin and Ozdemir found that addition been studied. The evaluation of the thickener performance of LBG, tragacanth gum, guar gum and xanthan gum to is considered on the basis of its effect upon sensory ketchup resulted in greater shear thinning properties while properties and rheology. Oat starch-xanthan gum combina- CMC showed marginal effect. Consistency index and tion has better thickening property compared to potato apparent viscosity increase with the addition of all hydro- starch-xanthan gum combination as evaluated from their colloids, but the increase is highest with the addition of energy of thixotropy.
Both potato starch and xanthan are guar and LBG, followed by xanthan and tragacanth and the anionic polysaccharides and hence are thermodynamically least with CMC. Koocheki et al.
HPMC containing rice cake batters produced after addition of guar gum. Table 2 Major hydrocolloid gelling agents and their characteristics Hydrocolloid as a gelling agent Characteristics Application in food Reference Modified starch Thermally irreversible opaque Dairy desserts Verbeken et al. The polysac- Gum arabic Acacia gum is widely used in the food charide concentration at which the sharp change in industry mainly to impart desirable qualities because of its viscosity occurs is referred to as the critical overlap influence over viscosity, body and texture.
The onset of as an emulsifier in beverage emulsions Buffo et al. Mothe and Rao in their study on the is exceeded. At low shear rates, the rate of disruption of entanglements is slower than or equal to the formation of new entanglements and Process of thickening thus exhibits Newtonian flow. The viscosity during this time is known as the zero-shear viscosity.
As shear rate is The application of a hydrocolloid depends on the knowl- increased, the rate of disruption also increases and exceeds edge and understanding of the process of thickening—an that of formation. At this point, viscosity begins to decrease important role of any hydrocolloid.
The functional roles of sharply as a function of shear rate. The viscosity of hydrocolloid inter-chain association in conformationally-ordered junction dispersions is also influenced by the polymer hydrodynam- zones Philips et al.
Phillips G.O., Williams P.A. (eds.) Handbook of hydrocolloids
It increases with molecular mass, chain rigidity The question that arises is how hydrocolloids thicken and electrostatic charge density, and is greater for linear solutions. The viscosity of polysaccharide dispersions arises compared to branched polysaccharides. Thus, amylose will predominantly from physical entanglement of conforma- have a higher intrinsic viscosity than amylopectin. In dilute dispersion, the Starch is the most commonly used hydrocolloid thick- individual molecules of hydrocolloids can move freely and ener, and is used both in the native and modified forms do not exhibit thickening.
In concentrated system, these Babic et al. Cold water does not dissolve starch but molecules begin to come into contact with one another; as the water is heated, it gradually penetrates the granules thus, the movement of molecules becomes restricted. The causing them to swell up.
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Thus, a marginal thickening transition from free moving molecules to an entangled occurs at this stage, and finally near the boiling point, the network is the process of thickening. Thus, hydrocolloid starch granules burst and release the inner components into thickeners can be considered as entanglement of network the liquid and marked thickening occurs. Other gums are producers. In cases where no enthalpic polymer-polymer often added to starch to improve the texture and mouthfeel.
Gels and gelling agents Intrinsic viscosity is an important parameter used to compare the viscosities of dispersions of hydrocolloids. They consist of polymer molecules cross- Mark-Houwink equation Eq. Agar and gelatin form gel by this According to this definition, a gel is a viscoelastic system mechanism Glicksman Hydrocolloids form gels by physical methyl cellulose, starch and globular proteins.
It is usually association of their polymer chains through hydrogen only where heat setting is required in foods eg, the use of bonding, hydrophobic association and cation mediated starch in sauces.
Though all hydrocolloids thicken aqueous dispersions, only a comparatively few gums form gels. Also the gels Role of junction zones in gelling thus formed vary widely in gel character and texture. Hence, knowledge of the conditions required for gelling of Junction zones play a very important role in the gelling particular hydrocolloid dispersion, the characteristics of the process of hydrocolloids de Vries They also markedly gel produced and the texture it confers are very important influence the characteristics and functional behaviour of a aspects to design a specific food formulation.
The important particular gel. The number of molecules that form a junction gums that find application in food as gelling agents include zone is an important gel property determinant.
During alginate, pectin, carrageenan, gellan, gelatin, agar, modified gelatin, junction zones are formed by three molecules starch, methyl cellulose and hydroxypropylmethyl cellu- through hydrogen bonding.
More the number of molecules in the junction zone, more rigid will be the gel. The dispersed polymer segments in dispersion in such a way so number of junction zones and number of molecules in the as to form a three-dimensional network that contains junction zones and the flexibility of the interrupting seg- solvent in the interstices. The associated regions known as ments are important for the characteristics of a set gel. Hydrocolloid mation before they break compared to alginate gels of almost gelation can involve a hierarchy of structures, the most the same strength.
The thermal behaviour of gels also differs common of which is the aggregation of primary inter-chain because of the junction zones. The weak hydrogen bonds. On the other hand, it is possible to physical arrangement of these junction zones within the make alginate gels that do not melt on boiling because of the network can be affected by various parameters like strength of calcium bridges in the junction zones.
One of the temperature, presence of ions and inherent structure of major factors influencing the strength of junction zones is hydrocolloid. For the gelation of hydrocolloids, the three their length.
Calcium bridging is cooperative, i. Solvent quality is also another important factor. Ionotropic gelation occurs via cross-linking of hydrocol- Hydrogen bonds in high methoxy pectin gels can only be loid chains with ions, typically a cation mediated gelation formed if the water activity is sufficiently reduced by process of negatively charged polysaccharides.
Examples of addition of sugar. Ionotropic gelation is gels like stacked double helix junctions in carrageenans, carried out by either diffusion setting or internal gelation. Typically used gelling concentra- commonly combined to achieve increased viscosity or tions of different hydrocolloid gelling agents in food are superior properties of food gels, such as higher elasticity summarized in Table 3.
Nussinovitch The blending of different polysac- In addition to having knowledge of the factors that affect charides offers an alternative route to the development of gel formation by hydrocolloids, it is also necessary to new textures.
The major interest lies in the development of characterize the gels formed by them. Microstructural and synergistic mixtures with improved or induced gelation. Rheological charac- when used singly. But together, they form gels because of terization of gels involves characterizing a gel on the basis synergistic interactions. The mixture of xanthan and of various parameters like modulus of elasticity, yield galactomannan is one of the oldest and most extensively stress, shear modulus, storage and loss modulus, complex studied synergistic gelling systems.
Xanthan shows quite viscosity, gel strength and compliance. These parameters spectacular synergistic interactions with other non-gelling are usually determined by conducting tests like compres- polysaccharides of galactomannan family leading to in- sion test, dynamic oscillatory rheometry, creep and texture crease in viscosity Casas and Garcia-Ochoa and gel profile analysis, etc. The sal texture measuring system, controlled stress rheometer.
Xanthan-guar mixtures exhibit synergistic increase istics forms an indispensable part of the study on gels. At higher concentrations, soft and products, wherein hydrocolloids are incorporated as elastic gels are formed with locust bean gum LBG. The Bayarri et al. Addition of sucrose results in an interaction of xanthan gum with galactomannan is depen- increase of true rupture stress in all these gels.
However, dent on the ratio of the mixture, pH and ionic environment. In addition, the main and Generally, the synergistic factors determining the gel sweetness are related with interaction with galactomannans is at its maximum in mechanical properties of gel like gel strength, rupture deionised water at neutral pH and it gets reduced at high stress, rupture strain and particularly with the amount of salt concentrations and low pH Sworn Besides, glucomannan KGM during gel formation.
Their syner- co-solutes like sucrose, concentration of hydrocolloid, gism produces thermoreversible physical gels at neutral pH.
Mixtures of xanthan and Marcotte et al. Kappa carageenans form gels in milk interactions of which, with other hydrocolloids have been at much lower concentrations because of the electrostatic exploited in several food formulations. The results in increased milk reactivity Snoeren et al. Use maximum interaction, and hence, peak rupture gel strength of carrageenan in tofu soybean curd significantly decreases occurs at ratios between These polymer combinations are used acetate are used.
The other important application of also be used for glazing of cake or they can be formulated carrageenan is in injected meat, in which only carrageenans to give clear water dessert gels with an elastic cohesive gel can be dispersed in brine without too high viscosity and texture like gelatin.In icings and toppings, fruit pie in mouth , and they are slow-setting; all these features make fillings and table jellies alginates are used but they are gelatin the preferred gelling agent in yoghurt products, low- incompatible with milk, except in the presence of calcium fat spreads and sugar confectionery.
He has published over papers concerned with aspects of protein chemistry and edited and contributed to several books in the same area. Free Shipping Free global shipping No minimum order. Gelatin has also been used in flavoured gelled milk desserts, either alone or in combination with carrageenan, and also in dessert creams. The role of each hydrocolloid in food formulations and product development has been discussed along with examples and methods of characterisation to indicate the increasing use of hydrocolloids as an important food additive.
Blackie Academic and Professional, in aqueous system under acidic conditions. The book is very food focused and therefore gums with predominantly industrial applications, such as HPMC, tend to be skipped over quite briefly. The current specification of hydrocolloids is to be found in the fourth edition Starches, the vast majority of gums, alginates and celluloses enjoy this wide authorisation.
Other applications of pectin include desserts, both water gels and milk based gels.
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